I may be mistaken but I understood that Borel developed his sigma algebra before Lebesgue developed his measure. If correct, then Borel can't have been trying to find a collection of sets in $\mathbb{R}$ that would support his student's measure. What was his motivation? Maybe my premise is wrong.
I've Googled and checked this exchange (and other similar exchanges) and I've not been able to get even a hint that this question has been asked.