As typically taught in high school, the voltage ($V$) across a capacitor is proportional to the charge ($Q$), which is expressed by the formula $Q=CV$, where $C$ is the capacitance.
I am interested in finding the earliest papers where this equation was stated and how it was demonstrated experimentally. Specifically, I would like to know how the charge and voltage were measured in these experiments.
You might argue that this is just the definition of capacitance, but if $Q$ were not proportional to $V$, it would not make sense. Therefore, some experimental work must have been done to verify this relationship.
I started by looking into Faraday's books on electricity but did not find relevant information.